Sodium Sulfide

Sodium sulfide, or Na2S, is an inorganic chemical compound with the formula of Na2S that has risen to prominence in the organic chemical industry. It's a powerful alkaline solution that smells like rotten eggs when exposed to moist air. Despite the fact that the solid-state is yellow, the solution is colourless. It's usually labelled as "sodium sulfide flakes" in the grades.

Sodium sulfide is a salt which plays an essential role in the organic chemistry industry. The formula for sodium sulfide is Na2S, or more commonly its hydrate Na2S·9H2O. Both the anhydrous and the hydrous salts are colourless solids. Sodium sulfide is a water-soluble compound, with a strongly alkaline solution. If the compound is exposed in the moist air, Na2S and its hydrates emit hydrogen sulfide. This emission smells like a rotten egg. The solid-state of sodium sulfide in solution is a yellow colour, and it comes as grades, known as sodium sulfide flakes. The IUPAC name of sodium sulfide is disodium sulfide. The oxidation number of sodium sulfide is -2, whereas its pH value is 10.4.

IUPAC Name – Sodium Sulfide

Sodium Sulfide Structure – Na

2

S

Na2S adopts the antifluorite structure.  This structure is obtained by exchanging the positions of anions and cations. This means that the Na+ occupy sites of the fluoride and  S2- hold the sites for Ca2+.

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Sodium Sulfide-Na

2

S Chemical Information

Na2S

Sodium Sulfide

Density

1.86 g/cm³

Molecular Weight /Molar Mass

78.0452 g/mol

Autoignition temperature

>480°C (896°F;753K)

Melting Point

1,176°C(2,149°F)

Chemical Formula

Na2S

Sodium Sulfide – Na

2

S – Physical Properties

Odour

Odor of rotten egg

Appearance 

Anhydrous yellow crystalline solids

Storage temperature

2-8°C

pH

10.4

Oxidation number

-2

Solubility

Insoluble in either ;slightly soluble in alcohol

Chemical Formula of sodium sulfide

Na2S

Physical Appearance

Colourless and hygroscopic solid

The odour of sodium sulfide

Rotten eggs

Density

1.856 g/cm3, for  anhydrous

1.58 g/cm3, for pentahydrate

1.43 g/cm3, for nonahydrate

Melting Point of sodium sulfide

1,176°C

Solubility

Slightly soluble in alcohol, Insoluble in ethers

Molar Mass of sodium sulfide

78.0452g/mol

Bond strength

2/2 = 1

Sodium Sulfide – Na

2

S – Chemical Properties

Sodium sulfide dissolves in water and forms the ions it needs. The following is the reaction.

Na2S + H2O → 2 Na+ + HS– + OH–

When heated, it quickly oxidized to generate sodium carbonate and sulphur dioxide.

2Na2S + 3O2 + 2CO2 → 2Na2CO3 + 2SO2

Polysulfides are formed when it reacts with sulphur.

2Na2S + S8 → 2Na2S5

• When sodium sulfide is dissolved in water, it forms its corresponding ions. The reaction of the same is given below:

Na2S + H2O → 2 Na+ + HS- + OH-

• Also, sodium sulfide oxidises quickly by heating. The results will be sodium carbonate and sulfur dioxide.

2Na2S + 3O2 + 2CO2 → 2Na2CO3 + 2SO2

• When sodium sulfide goes under oxidation with hydrogen peroxide, it gives sodium sulfate as a result.

Na2S + 4 H2O2 → 4 H2O + Na2SO4

• If sodium sulfide is reacted with sulfur, it forms a polysulfide, given as below:

2Na2S + S8 → 2Na2S5

How is Sodium Sulfide Produced?

In industries, Na2S is produced by a carbothermic reduction reaction. In this reduction reaction, carbon is used as a reducing agent.

Similarly, for sodium sulfide, sodium sulfate is reacted by coal. 

Na2SO4 + 2 C → Na2S + 2 CO2 

In laboratories, the sodium sulfide salt is usually prepared by the reduction method. Sodium sulphur is reacted by anhydride ammonia, or through sodium in dry THF, with the help of naphthalene as a catalyst. The result formed will be sodium naphtha lenoide.

2Na + S → Na2S

Sodium Sulfide (Na

2

S) has a Variety of Applications

• It is employed as an oxygen scavenger and a metal precipitant in water treatment.

• Used as a bleaching agent in the textile sector to preserve developer solutions from oxidation in the photographic business.

• It's used to make elastomeric synthetic materials, sulphur colours, and other things.

• In the crafting process, it's mostly used in the pulp and paper sector. It improves the sulphate cooking process' selectivity and speeds up the delignification process.

Uses of Sodium Sulfide

• In the paper and pulp business, it's used in the kraft process.

• In water treatment, it's used as an oxygen scavenger.

• In the textile sector, it is used as a bleaching agent.

• Sodium sulfide is mainly used in the pulp and paper industry for the kraft process. As in the kraft process, wood is converted into wood pulp, sodium hydroxide and sodium sulfide help to dissolve the lignin of wood fibre.

• This compound is used in water treatment. In this method, sodium sulfide acts as an oxygen scavenger agent

• For chemical photography, sodium sulfide is used as a metal precipitant for toning black and white photographs

• In the textile industry, sodium sulfide is used as a bleaching agent, dechlorinating agent and also desulphurising agent.

• In the production of rubber chemicals, sulfur dyes and other chemical compounds are used.

• Used in various applications like ore flotation, dye-making, oil recovery and detergent. 
  
  

Safety Measures: 

• Used as an unhairing agent in the liming process during leather production.

• Because sodium sulfide is a strong alkaline, it causes skin burns.

• When sodium sulfides combine with acid quickly, it produces poisonous hydrogen sulfide.

Side Effects of Sodium Sulfide

It's normal for the top layer of skin to peel slightly. Irritation, redness, and scaling of the skin are also possible side effects. Stop taking this medication and inform your doctor or pharmacist right away if any of these effects persist or worsen.

Keep in mind that your doctor ordered this medication because he/ she believes the benefit to you outweighs the risk of adverse effects. The majority of people who take this medicine do not have any substantial adverse effects.

Sodium sulfide is strongly alkaline. It can cause significant skin burns. Reacting with acid can form hydrogen sulfide, which is a highly toxic and flammable gas. In reduced ventilation spaces, hydrogen sulfide accumulates at the bottom. To use hydrogen sulfide, one should keep the safety data sheet with them.

Na2S + 2HCl → 2NaCl + H2S(g)

What's the Type of Bonding of Sodium Sulfide? 

Sodium sulfide compound is an ionic compound. There are 2 Na atoms per 1 Sulfide atom. It has a central Sulfur atom encircled by 4 Oxygens in covalent bonds.  The Sodium atoms and Sulfur or Oxygen atoms in the compound exchange their electrons. Moreover, Sulfur is in group 6, and it requires two more electrons to attain a noble gas state of Argon.

Likewise, the remaining 2 Sodium atoms want to lose 1 electron each to become the noble gas state of Neon. Thus, the 2 Sodium atoms each provide one electron to the Sulfur atom, helping it to be stable in its outer shell.

Since the Sodium atoms give away all its extra electrons to its outermost shell, the two atoms attain the noble gas configuration of Neon and hence become stable.